SIOC OpenIR  > 中科院有机氟化学重点实验室
Synthesis and luminescent properties of Zn complex based on 8-hydroxyquinoline group containing 3,5-bis(trifluoromethyl) benzene unit with unique crystal structure
其他题名含有3,5-二(三氟甲基)苯基的8-羟基喹啉与锌的配合物的晶体的合成和发光研究
Huo YP(霍延平); Zhu SZ(朱仕正); Hu S(胡胜)
2010
发表期刊Tetrahedron
ISSN0040-4020
卷号66期号:45页码:8635-8640
摘要The use of a novel 2-substituted-8-hydroxyquinoline ligand (E)-2-{2-[3,5-bis(trifluoromethyl)phenyl] ethenyl}-8-hydroxyquinoline(4, BFHQ) characterized by EIMS, H-1 NMR spectroscopy, elemental analysis, and FTIR spectroscopy enabled the isolation of a trimeric Zn(II) complex with the formula Zn-3(BFHQ)(6) (5, Scheme 1). X-ray structural analysis shows that 5 exhibits a trinuclear core, which is bridged by four 8-hydroxyquinoline rings. The trinuclear core is surrounded by three pairs of BFHQ ligands with offset pi-pi stacking, showing propeller-like molecular structure. The aggregation behavior of Zn(AcO)(2) and the ligand 4 in solution was investigated by UV-vis. The luminescence properties of compound 5 were investigated by UV-vis and fluorescence spectra at room temperature. The experimental results show that the complex 5 emits yellow luminescence at 553 nm (lambda(em, max)) in DMSO solution and at 610 nm (lambda(em, max)) in solid state. The thermogravimetric analysis was carried out to examine the thermal stability. (C) 2010 Elsevier Ltd. All rights reserved.
学科领域有机氟化学
部门归属广东工业大学; 中国科学院上海有机化学研究所
URL查看原文
收录类别SCI
语种英语
WOS记录号WOS:000283696400008
引用统计
被引频次:28[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/14474
专题中科院有机氟化学重点实验室
通讯作者Huo YP(霍延平); Zhu SZ(朱仕正)
推荐引用方式
GB/T 7714
Huo YP,Zhu SZ,Hu S. Synthesis and luminescent properties of Zn complex based on 8-hydroxyquinoline group containing 3,5-bis(trifluoromethyl) benzene unit with unique crystal structure[J]. Tetrahedron,2010,66(45):8635-8640.
APA 霍延平,朱仕正,&胡胜.(2010).Synthesis and luminescent properties of Zn complex based on 8-hydroxyquinoline group containing 3,5-bis(trifluoromethyl) benzene unit with unique crystal structure.Tetrahedron,66(45),8635-8640.
MLA 霍延平,et al."Synthesis and luminescent properties of Zn complex based on 8-hydroxyquinoline group containing 3,5-bis(trifluoromethyl) benzene unit with unique crystal structure".Tetrahedron 66.45(2010):8635-8640.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
2010002.pdf(816KB) 开放获取--请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[霍延平]的文章
[朱仕正]的文章
[胡胜]的文章
百度学术
百度学术中相似的文章
[霍延平]的文章
[朱仕正]的文章
[胡胜]的文章
必应学术
必应学术中相似的文章
[霍延平]的文章
[朱仕正]的文章
[胡胜]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。