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Self-assembly of two novel cadmium(II) complexes: One from tripodal imine-phenol ligand and the other from in situ partial degradation of dipolar imine-phenol ligand
其他题名Self-assembly of two novel cadmium(II) complexes: One from tripodal imine-phenol ligand and the other from in situ partial degradation of dipolar imine-phenol ligand
Zhou XX(周秀霞); Cai YP(蔡跃鹏); Zhu SZ(朱仕正); Zhan QG(战庆光); Liu MS(刘茂生); Zhou ZY(周正源); Chen L(陈丽)
2008
发表期刊Cryst. Growth Des.
ISSN1528-7483
卷号8期号:7页码:2076-2079
摘要Through different synthetic strategies, two novel cadmium(II) complexes have been synthesized and characterized. The first mesocate complex Cd3L21 (1) with S-6 symmetry based on tris[(2-salicylaldeneimino)ethyl]-amine (H3L1 or H(3)trensal) is constructed from the self-assembly of Cd2+ ion and two chiral building block units, Delta- and Lambda-[Cd(trensal)](-), in which the coordination numbers of six and seven for Cd(II) ions are rarely found in one discrete compound without any auxiliary ligand. However, under the same reaction conditions. CdL3(H2O)(NO3) (2) with N3O4 donors is obtained from Cd-II coordination induced partial hydrolysis of dipolar imine-phenol Schiff base ligand N,N'-bis(salicylidene)-3, 6-dioxa-1,8-diaminooctane (H2L2), which provides the first example of hydrated Cd-II salt promoting partial degradation of the imine-phenol ligand. The strong fluorescence emission of 1 makes it a potentially useful photoactive material for its high thermal and chemical stability.
学科领域有机化学
部门归属华南师大; 上海有机所
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收录类别SCI
语种英语
WOS记录号WOS:000257408200009
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被引频次:54[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/14444
专题中科院有机氟化学重点实验室
通讯作者Cai YP(蔡跃鹏); Zhu SZ(朱仕正)
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GB/T 7714
Zhou XX,Cai YP,Zhu SZ,et al. Self-assembly of two novel cadmium(II) complexes: One from tripodal imine-phenol ligand and the other from in situ partial degradation of dipolar imine-phenol ligand[J]. Cryst. Growth Des.,2008,8(7):2076-2079.
APA 周秀霞.,蔡跃鹏.,朱仕正.,战庆光.,刘茂生.,...&陈丽.(2008).Self-assembly of two novel cadmium(II) complexes: One from tripodal imine-phenol ligand and the other from in situ partial degradation of dipolar imine-phenol ligand.Cryst. Growth Des.,8(7),2076-2079.
MLA 周秀霞,et al."Self-assembly of two novel cadmium(II) complexes: One from tripodal imine-phenol ligand and the other from in situ partial degradation of dipolar imine-phenol ligand".Cryst. Growth Des. 8.7(2008):2076-2079.
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