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学科主题: 有机化学
题名: Self-assembly of two novel cadmium(II) complexes: One from tripodal imine-phenol ligand and the other from in situ partial degradation of dipolar imine-phenol ligand
其他题名: Self-assembly of two novel cadmium(II) complexes: One from tripodal imine-phenol ligand and the other from in situ partial degradation of dipolar imine-phenol ligand
作者: Zhou XX(周秀霞) ; Cai YP(蔡跃鹏) ; Zhu SZ(朱仕正) ; Zhan QG(战庆光) ; Liu MS(刘茂生) ; Zhou ZY(周正源) ; Chen L(陈丽)
通讯作者: 蔡跃鹏 ; 朱仕正
刊名: Cryst. Growth Des.
发表日期: 2008
卷: 8, 期:7, 页:2076-2079
收录类别: SCI
部门归属: 华南师大; 上海有机所
英文摘要: Through different synthetic strategies, two novel cadmium(II) complexes have been synthesized and characterized. The first mesocate complex Cd3L21 (1) with S-6 symmetry based on tris[(2-salicylaldeneimino)ethyl]-amine (H3L1 or H(3)trensal) is constructed from the self-assembly of Cd2+ ion and two chiral building block units, Delta- and Lambda-[Cd(trensal)](-), in which the coordination numbers of six and seven for Cd(II) ions are rarely found in one discrete compound without any auxiliary ligand. However, under the same reaction conditions. CdL3(H2O)(NO3) (2) with N3O4 donors is obtained from Cd-II coordination induced partial hydrolysis of dipolar imine-phenol Schiff base ligand N,N'-bis(salicylidene)-3, 6-dioxa-1,8-diaminooctane (H2L2), which provides the first example of hydrated Cd-II salt promoting partial degradation of the imine-phenol ligand. The strong fluorescence emission of 1 makes it a potentially useful photoactive material for its high thermal and chemical stability.
语种: 英语
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WOS记录号: WOS:000257408200009
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14444
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Zhou XX,Cai YP,Zhu SZ,et al. Self-assembly of two novel cadmium(II) complexes: One from tripodal imine-phenol ligand and the other from in situ partial degradation of dipolar imine-phenol ligand[J]. Cryst. Growth Des.,2008,8(7):2076-2079.
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