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学科主题: 有机氟化学
题名: Nucleophilic addition of ethyl 3-bromodifluoromethyl-3-benzyloxyacrylate to imines: An effective entry to novel gem-difluorinated amino esters and their derivatives
其他题名: 3-溴二氟甲基-3-苄氧基丙烯酸乙酯的亲核加成——一种有效的二氟化氨基酸酯及其衍生物的合成方法
作者: Peng WM(彭伟民) ; Zhao JW(赵经纬) ; He P(何萍) ; Zhu SZ(朱仕正)
通讯作者: 朱仕正
刊名: Synlett
发表日期: 2006-01-01
期: 2, 页:296-300
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: Zinc- or tetrakis(dimethylamino)ethylene (TDAE)-mediated nucleophilic addition of ethyl 3-bromodifluoromethyl-3-benzyloxyacrylate to imines afforded gem-difluorovinyl substituted beta-amino esters (alpha-addition product) and gem-difluorinated delta-amino esters (gamma-addition product) or their cyclized derivatives, depending on the mediator and the nature of substituents on the imines.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000235069300027
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14400
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Peng WM,Zhao JW,He P,et al. Nucleophilic addition of ethyl 3-bromodifluoromethyl-3-benzyloxyacrylate to imines: An effective entry to novel gem-difluorinated amino esters and their derivatives[J]. Synlett,2006(2):296-300.
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