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学科主题: 有机氟化学
题名: One-pot three-component reaction of fluoroalkanesulfonyl azide, vinyl ether and aldehyde: the formation of polysubstituted fluorinated oxazolidines diastereoselective; oxazolidine
其他题名: 氟烷基磺酰叠氮, 烯基醚和醛的三组分一锅反应生成多取代含氟噁唑烷
作者: He P(何萍) ; Zhu SZ(朱仕正)
通讯作者: 朱仕正
刊名: Tetrahedron
发表日期: 2005-01-01
卷: 61, 期:25, 页:6088-6096
收录类别: SCI
部门归属: 上海有机化学研究所元素有机化学研究室; 华南师范大学
英文摘要: Efficient and diastereoselective synthesis of highly substituted fluorinated oxazolidines was achieved via a one-pot three-component reaction of fluoroalkanesulfonyl azides 1, vinyl ether 2 and various aldehydes at 0 degrees C within 10 min in moderate to good diastereoselectivities (synlanti). A competing process could be involved in the initial step and an unstable fluorinated aziridine was postulated as the intermediate for these reactions. Additionally, rational transition states were also proposed to elucidate the diastereoselectivities. This synthetic method provides a convenient and expeditious access to N-per(poly)fluoroalkanesulfonyl oxazolidines. (c) 2005 Elsevier Ltd. All rights reserved.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14350
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
He P,Zhu SZ. One-pot three-component reaction of fluoroalkanesulfonyl azide, vinyl ether and aldehyde: the formation of polysubstituted fluorinated oxazolidines diastereoselective; oxazolidine[J]. Tetrahedron,2005,61(25):6088-6096.
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