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学科主题: 有机氟化学
题名: Study on the reactions of fluoroalkanesulfonyl azides with indole derivatives cycloaddition; triazolines; diazo transfer
其他题名: 氟烷基磺酰叠氮与吲哚衍生物反应的研究
作者: He P(何萍) ; Zhu SZ(朱仕正)
通讯作者: 朱仕正
刊名: J. Fluor. Chem.
发表日期: 2005-01-01
卷: 126, 期:5, 页:825-830
收录类别: SCI
部门归属: 上海有机化学研究所元素有机研究室; 华南师范大学
英文摘要: The reactions of fluoroalkanesulfonyl azides 1 with different indole derivatives have been studied in detail. Treatment of 1 with equimolar amount of 1,3-dimethylindole 3 in 1,4-dioxane at room temperature afforded 2-(1,3-dimethyl-1,3-dihydro-indolinylidene) fluoroalkane-sulfonylimines 5 in moderate to good yields. However, under the same reaction conditions, in the case of 1 with 1,2-dimethylindole 4, the corresponding 2-fluoroalkanesulfonyl (1,2-dimethyl-1H-indol-3-yl)-amide 6 was obtained in moderate yields. In addition, the reactions of I and indole 7 gave different products under different conditions. Possible mechanisms of these reactions were proposed. (c) 2005 Elsevier B.V. All rights reserved.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14348
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
He P,Zhu SZ. Study on the reactions of fluoroalkanesulfonyl azides with indole derivatives cycloaddition; triazolines; diazo transfer[J]. J. Fluor. Chem.,2005,126(5):825-830.
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