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学科主题: 有机氟化学
题名: Study on the reactions of pyridine with fluorine-containing compounds in the gas phase by electron impact/Fourier transfer ion cyclotron resonance mass spectrometry
其他题名: 电子轰击傅立叶转换离子回旋共振质谱法在吡啶与含氟化合物的气相的反应中的运用
作者: He P(何萍) ; Guo YL(郭寅龙) ; Zhu SZ(朱仕正)
通讯作者: 郭寅龙 ; 朱仕正
刊名: J. Fluor. Chem.
发表日期: 2004
卷: 125, 期:10, 页:1537-1541
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: The gas-phase ion-molecule reactions of pyridine and fluorine-containing compounds have been studied by the electron impact/Fourier transfer ion cyclotron resonance mass spectrometry (EI/FTICRMS). Comparing the reaction of the standard sample perfluorotributylamine (PFTBA), in the case of 3-oxa-5-iodo-octafluoropentylsulfonyl azide (ICF2CF2OCF2CF2SO2N3) a series of addition-elimination products and loss 28 from the expected adducts were obtained. A possible reaction mechanism was discussed, which was consistent with the results obtained in the condensed phase. These results demonstrated that EI/FTICRMS is a complementary technique for study of the organic reactions. (C) 2004 Published by Elsevier B.V.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000224445400023
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14334
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
He P,Guo YL,Zhu SZ. Study on the reactions of pyridine with fluorine-containing compounds in the gas phase by electron impact/Fourier transfer ion cyclotron resonance mass spectrometry[J]. J. Fluor. Chem.,2004,125(10):1537-1541.
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