SIOC OpenIR  > 中科院有机氟化学重点实验室
Transition-metal-catalyzed formation of trans alkenes via coupling of aldehydes
Alternative Title过渡金属催化醛的偶联形成完全反式烯烃
Zhu SF(祝诗发); Liao YX(廖远熹); Zhu SZ(朱仕正)
2004
Source PublicationOrg. Lett.
ISSN1523-7060
Volume6Issue:3Pages:377-380
AbstractRh-2(OAC)(4) catalyzed the formation of exclusively trans fluorinated alkenes from aldehydes and pentafluorobenzaldehyde tosylhydrazone salts, which were readily prepared from pentafluorobenzaldehyde using the Bamford-Stevens reaction. A series of pentafluorophenyl-containing alkenes were synthesized from aldehydes in moderate to good yields under mild reaction conditions in a one-pot reaction. It is the first report of coupling two different aldehydes to form exclusively trans alkenes.
Subject Area金属有机化学
Department中国科学院上海有机化学研究所元素有机实验室
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Indexed BySCI
Language英语
WOS IDWOS:000188596200018
Citation statistics
Cited Times:30[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/14328
Collection中科院有机氟化学重点实验室
Corresponding AuthorZhu SZ(朱仕正)
Recommended Citation
GB/T 7714
Zhu SF,Liao YX,Zhu SZ. Transition-metal-catalyzed formation of trans alkenes via coupling of aldehydes[J]. Org. Lett.,2004,6(3):377-380.
APA 祝诗发,廖远熹,&朱仕正.(2004).Transition-metal-catalyzed formation of trans alkenes via coupling of aldehydes.Org. Lett.,6(3),377-380.
MLA 祝诗发,et al."Transition-metal-catalyzed formation of trans alkenes via coupling of aldehydes".Org. Lett. 6.3(2004):377-380.
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