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学科主题: 有机氟化学
题名: Reactions of fluoroalkanesulfonyl azides with vinyl ether and tetrakis(dimethylamino)ethylene
其他题名: 氟烷基磺酰叠氮与烯基醚以及TDAE反应研究
作者: Zhu SZ(朱仕正) ; He P(何萍) ; Zhao JW(赵经纬) ; Cai X(蔡娴)
通讯作者: 朱仕正
刊名: J. Fluor. Chem.
发表日期: 2004
卷: 125, 期:3, 页:445-450
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所元素有机实验室
英文摘要: The reactions of fluoroalkanesulfonyl azides 1 with some electron-rich olefins have been studied. Alkyl vinyl ethers reacted with 1 readily at 0 degreesC or room temperature (RT) and did not give the corresponding N-fluoroalkanesulfonyl azilidines but 1-fluoroalkanesulfonyl-1,2,3-triazolines 3, which decomposed slowly at room temperature to form 1,4-fluoroalkanesulfonyl-2,5-alkoxyl-piperazines 4 with elimination of nitrogen gas. In contrast, more electron-rich alkene, tetrakis(dimethylamino)ethylene (TDAE) reacted with 1 affording N-fluoroalkanesulfonyl bis(dimethylamino)amidines 6 accompanying the release of N-2. Reaction mechanisms are discussed. (C) 2003 Elsevier B.V. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000220050100012
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14324
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Zhu SZ,He P,Zhao JW,et al. Reactions of fluoroalkanesulfonyl azides with vinyl ether and tetrakis(dimethylamino)ethylene[J]. J. Fluor. Chem.,2004,125(3):445-450.
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