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学科主题: 有机氟化学
题名: Structural determination of a zinc reagent from ethyl 3-bromodifluoromethyl-3-benzyloxyacrylate and its reactions with aldehydes
其他题名: 3-溴二氟甲基-3-苄基丙烯酸乙酯制成的锌试剂的结构确定及其与醛的反应研究
作者: Peng WM(彭卫民) ; He P(何萍) ; Zhu SZ(朱仕正) ; Li ZT(黎占亭)
通讯作者: 朱仕正
刊名: Tetrahedron Lett.
发表日期: 2004
卷: 45, 期:18, 页:3677-3680
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所元素有机实验室
英文摘要: The reactivity of ethyl 3-bromodifluoromethyl-3-benzyloxyacrylate as a novel gem-difluoromethylene synthon was investigated. F-19 NMR spectra of its zinc reagent in THF and DMF indicate unambiguously that the active species exists as the gamma-carbon metallated form. Moreover, promoted by zinc or TDAE, a complete control of the addition reaction mode (alpha or gamma) of this acrylate with aldehydes can be accomplished. (C) 2004 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000221022500033
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14320
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Peng WM,He P,Zhu SZ,et al. Structural determination of a zinc reagent from ethyl 3-bromodifluoromethyl-3-benzyloxyacrylate and its reactions with aldehydes[J]. Tetrahedron Lett.,2004,45(18):3677-3680.
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