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学科主题: 有机氟化学
题名: Co-existing intermolecular halogen bonding and hydrogen bonding in the compound trans-5,10-bis(1-bromodifluoro-acetyl-1-ethoxycarbonyl-methylidene)thian threne
其他题名: 反式-5,10-二-(1-二氟一溴乙酰基-1-乙氧羰基亚甲基)噻嗯化合物中的分子内氢键与卤键共存作用
作者: Zhu SF(祝诗发) ; Zhu SZ(朱仕正) ; Liao YX(廖远熹) ; Huang CF(黄超峰) ; Li ZT(黎占亭)
通讯作者: 朱仕正 ; 黎占亭
刊名: Chin. J. Chem.
发表日期: 2004-01-01
卷: 22, 期:9, 页:896-898
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所元素有机实验室
英文摘要: Trans-5,10-bis(1-bromodifluoroacetyl-1-ethoxycarbonyl-methylidene)thiant hrene (1b) was prepared from the reaction of BrCF2COC(N-2)CO2Et with thianthrene. X-ray single crystal diffraction analysis showed that the intermolecular halogen bonding and hydrogen bonding coexisted in this compound. The bromine atom acted as an electron acceptor in the halogen bond and an electron donor in the hydrogen bond. It is the first example that the bromine atom acted as such a dual role in the hydrogen and halogen bond.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14312
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Zhu SF,Zhu SZ,Liao YX,et al. Co-existing intermolecular halogen bonding and hydrogen bonding in the compound trans-5,10-bis(1-bromodifluoro-acetyl-1-ethoxycarbonyl-methylidene)thian threne[J]. Chin. J. Chem.,2004,22(9):896-898.
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