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学科主题: 有机氟化学
题名: The reaction of per(poly)fluoroalkanesulfonyl azides with tertiary and secondary amines: generation and trapping of enamines
其他题名: 全氟或多氟磺酰叠氮与二级或三级胺反应:捕获得到烯胺
作者: Xu Y(许勇) ; Zhu SZ(朱仕正)
通讯作者: 朱仕正
刊名: Tetrahedron
发表日期: 2001
卷: 57, 期:20, 页:4337-4341
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所元素有机化学实验室
英文摘要: Per(poly)fluoroalkanesulfonyl azides decomposed readily at 0℃ or ambient temperture in the presence of tertiary or secondary amines via a single electron transfer process and gave the corresponding fluoroalkanesulfonyl amides and N-fluoroalkanesulfonyl amidines. The formation of amidines was reasonably explained in terms of trapping of N-substituted vinylamine generated in situ with the azides.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000168781400009
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14262
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Xu Y,Zhu SZ. The reaction of per(poly)fluoroalkanesulfonyl azides with tertiary and secondary amines: generation and trapping of enamines[J]. Tetrahedron,2001,57(20):4337-4341.
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