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学科主题: 有机氟化学
题名: Syntheses and reactions of N-Perfluoroalkanesulfonylimino sulfurous dichlorides
其他题名: RfSO=2N=SCl=2 的合成及其反应研究
作者: Xu B(许斌) ; Xu GL(许国林) ; Qin CY(钦朝岳) ; Xu Y(许勇) ; Chu QL(储千里) ; Zhu SZ(朱仕正)
刊名: Heteroatom Chem.
发表日期: 1999
卷: 10, 期:1, 页:41-48
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所有机氟化学开放实验室
英文摘要: Treatment of N,N-dichloroperfluoroalkanesulfonylamines with sulfur powder at room temperature gave the title products R=1SO=2N=SCl=2 in good yields. They reacted readily with dimethyl sulfoxide, chloral, DMF, benzophenone, and similar compounds to form to corresponding imines R=1SO=2N-YR^1R^2(Y:S,C). A reaction mechanism, one involving formation of a four-membered intermediate, is proposed.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000078409400008
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14208
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Xu B,Xu GL,Qin CY,et al. Syntheses and reactions of N-Perfluoroalkanesulfonylimino sulfurous dichlorides[J]. Heteroatom Chem.,1999,10(1):41-48.
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