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学科主题: 有机氟化学
题名: Reactions of 5-trifluoroacetyl-3,4-dihydro-2H-pyran with zinc reagents
其他题名: 5-三氟乙酰基-3,4-二氢吡喃与锌试剂的反应
作者: Zhu SZ(朱仕正) ; Qin CY(钦朝岳) ; Xu GL(许国林) ; Chu QL(储千里) ; Huang QC(黄其辰)
通讯作者: 朱仕正
刊名: J. Fluor. Chem.
发表日期: 1999-01-01
卷: 99, 页:141-144
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所有机氟化学开放实验室; 北京大学
英文摘要: One pot reaction of 5-trifluoroacetyl-3,4-dihydro-2H-pyran with alkyl bromides RBr in the presence of zinc powder gave the corresponding alcohol (CH=2)=3OCH=CC(R)(CF=3)OH (R: CH=2CO=2Me, 3a; CH=2=CHCH=2- 3b); 3a readily hydrolysed to the corresponding carboxylic acid under dilute acidic conditions, intramolecular cyclo addition of this acid afforded a bicyclo lactone.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14206
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Zhu SZ,Qin CY,Xu GL,et al. Reactions of 5-trifluoroacetyl-3,4-dihydro-2H-pyran with zinc reagents[J]. J. Fluor. Chem.,1999,99:141-144.
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