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Study on tonghaosu and its analogs: Isolation, structure identification and synthesis of antifeedant B-ring-homo-tonghaosu
其他题名具有拒食活性的茼蒿素B环同系物的分离,鉴定以及合成
Chen L(陈立); Yin BL(尹标林); Xu HH(徐汉虹); Qiu MH(邱明华); Wu YL(吴毓林)
2004
发表期刊Chin. J. Chem.
ISSN1001-604X
卷号22期号:1页码:92-99
摘要The methanolic extract from a Chinese endemic Chrysanthemum plant, Dendranthema indicum var. aromaticum, was found to show high antifeeding activity against Pieris brassicae L., and by bioassay-guided separation, the active component, B-ring-homo-tonghaosu, 2-(2',4'-hexadiynylidene)-1,6-dioxaspiro-[4,5]-dec-3-ene (2) was isolated. Its structure was elucidated by comparing its spectroscopic data with those of 2 reported in the literatures. Furthermore new convenient total synthesis methods of B-ring-homo-tonghaosu were also developed to confirm its structure and make its further application in crop protection available. In addition, extensive comparison of spectroscopic data showed that the structure of compound 21 reported in literature should be revised to 2.
学科领域生命有机化学
部门归属中国科学院上海有机化学研究所生命有机化学实验室; 华南农大; 昆明植物所
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收录类别SCI
语种英语
WOS记录号WOS:000187998900019
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文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/14092
专题生命有机化学国家重点实验室
通讯作者Wu YL(吴毓林)
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GB/T 7714
Chen L,Yin BL,Xu HH,et al. Study on tonghaosu and its analogs: Isolation, structure identification and synthesis of antifeedant B-ring-homo-tonghaosu[J]. Chin. J. Chem.,2004,22(1):92-99.
APA 陈立,尹标林,徐汉虹,邱明华,&吴毓林.(2004).Study on tonghaosu and its analogs: Isolation, structure identification and synthesis of antifeedant B-ring-homo-tonghaosu.Chin. J. Chem.,22(1),92-99.
MLA 陈立,et al."Study on tonghaosu and its analogs: Isolation, structure identification and synthesis of antifeedant B-ring-homo-tonghaosu".Chin. J. Chem. 22.1(2004):92-99.
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