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学科主题: 生命有机化学
题名: Hydroamination of olefin in a special conjugated spiroketal enol ether system, diastereoselective synthesis of amino-containing tonghaosu analogs
其他题名: 共轭螺环烯醇醚的双键的氢胺化反应:立体选择性合成含氨基的茼蒿素类似物
作者: Yin BL(尹标林) ; Hu TS(胡泰山) ; Wu YL(吴毓林)
通讯作者: 吴毓林
刊名: Tetrahedron Lett.
发表日期: 2004
卷: 45, 期:9, 页:2017-2021
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所生命有机化学实验室
英文摘要: Lithium amide reacted with spiroketal enol ether characterized tonghaosu analog at -78degreesC to give the only hydroamination product 4 in a highly regio- and diastereoselective manner. At a higher temperature, -40degreesC, the presence of free amine was critical for the hydroamination to take place; otherwise, rearrangement of tonghaosu analog to 2,3-dihydrofuran derivative like 6 was the only reaction. (C) 2004 Published by Elsevier Ltd.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000189116200047
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14086
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Yin BL,Hu TS,Wu YL. Hydroamination of olefin in a special conjugated spiroketal enol ether system, diastereoselective synthesis of amino-containing tonghaosu analogs[J]. Tetrahedron Lett.,2004,45(9):2017-2021.
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