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学科主题: 天然产物有机化学
题名: Acid catalysed rearrangement of a spiroketal enol ether. An easy synthesis of chrycorin
其他题名: 一种螺缩酮烯醇醚的酸催化重排. Chrycorin 的一种简便合成
作者: Yin BL(尹标林) ; Wu YK(伍贻康) ; Wu YL(吴毓林)
通讯作者: 吴毓林
刊名: J. Chem. Soc.-Perkin Trans. 1
发表日期: 2002
期: 15, 页:1746-1747
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所生命有机化学实验室
英文摘要: Tonghaosu, 2-[(Z)-hexa-2,4--diynylidene]-1,6-dioxaspiro[4,4]non-3ene(1a), and its spiroketal enol ether analogues (1b-d and 2) were efficiently converted into interesting cyclopentenone derived oxabicyclic compounds. By applying this reaction protocol the natural product chrycorin was easily synthesized in its racemic form. A reaction mechanism for this is proposed.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000177073300003
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14024
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Yin BL,Wu YK,Wu YL. Acid catalysed rearrangement of a spiroketal enol ether. An easy synthesis of chrycorin[J]. J. Chem. Soc.-Perkin Trans. 1,2002(15):1746-1747.
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