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学科主题: 生命有机化学
题名: A straightforward synthesis of DAH (3-deoxy-D-arabino-hept-2-ulosonic acid)and DRH(3-deoxy-D-ribo-hept-2-ulosonic acid
其他题名: DAH (3-deoxy-D-arabino-hept-2-ulosonic acid) 和 DRH(3-deoxy-D-ribo-hept-2-ulosonic acid)的简捷合成
作者: Liu KG(刘克刚) ; Hu SG(胡守刚) ; Wu YK(伍贻康) ; Yao ZJ(姚祝军) ; Wu YL(吴毓林)
通讯作者: 吴毓林
刊名: J. Chem. Soc.-Perkin Trans. 1
发表日期: 2002-01-01
期: 16, 页:1890-1895
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所生命有机化学实验室
英文摘要: Based on the oxidation of corresponding terminal alkynes to α-keto esters, DAH (3-deoxy-D-arabino-hept-2-ulosonic acid) in its pyranose form and DRH (3-deoxy-D-ribo-hept-2-ulosonic acid) in its protected pyranose-furanose mixture form were efficiently synthesized. These terminal alkynes were in turn obtained by C^1-or C^3-homologation of corresponding protected sugars, respectively. Along with the application of this strategy, the syntheses of two C^6-ulosonic acids, 3-deoxy-D-erythro-hex-2-ulosonic acid and 3-deoxy-L-erythro-hex-2-ulosonic acid in their protected pyranose form, were also described.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14022
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Liu KG,Hu SG,Wu YK,et al. A straightforward synthesis of DAH (3-deoxy-D-arabino-hept-2-ulosonic acid)and DRH(3-deoxy-D-ribo-hept-2-ulosonic acid[J]. J. Chem. Soc.-Perkin Trans. 1,2002(16):1890-1895.
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