中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 中科院有机氟化学重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: TiCl(4)-Promoted Mukaiyama Aldol Reaction of Fluorinated Silyl Enolates for the Construction of a Quaternary Carbon Center
其他题名: 构筑季碳中心的四氯化钛催化的氟代烯醇硅醚的Mukaiyama反应
作者: Wang WG(王文贵) ; Chen QY(陈庆云) ; Guo Y(郭勇)
通讯作者: 郭勇
刊名: Synlett
发表日期: 2011-01-01T00:00:00Z
期: 18, 页:2705-2708
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: A method for the preparation of alpha-fluoro-beta-hydroxyphenones from Mukaiyama aldol reactions of various aldehydes and fluorinated silyl enolates was reported. The reaction was promoted by TiCl(4) and afforded the desired products in good to excellent yields. The relative stereochemistry of the products was determined by X-ray analysis of single crystals of syn-2-fluoro-3-hydroxy-2-methyl-1,3-diphenylpropan-1-one and anti-2-fluoro-3-hydroxy-2,4,4-trimethyl-1-phenylpentan-1-one.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/13712
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2011487.pdf(113KB)----开放获取--View Download

Recommended Citation:
Wang WG,Chen QY,Guo Y. TiCl(4)-Promoted Mukaiyama Aldol Reaction of Fluorinated Silyl Enolates for the Construction of a Quaternary Carbon Center[J]. Synlett,2011(18):2705-2708.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[王文贵]'s Articles
[陈庆云]'s Articles
[郭勇]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[王文贵]‘s Articles
[陈庆云]‘s Articles
[郭勇]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2011487.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace