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学科主题: 有机氟化学
题名: Generation of the CF(3) radical from trifluoromethylsulfonium triflate and its trifluoromethylation of styrenes
其他题名: 由三氟甲基锍盐产生的三氟甲基自由基与芳基乙烯的反应
作者: Zhang CP(张成潘) ; Wang ZL(王宗令) ; Chen QY(陈庆云) ; Zhang CT(张春桃) ; Gu YC(顾玉诚) ; Xiao JC(肖吉昌)
通讯作者: 肖吉昌
刊名: Chem. Commun.
发表日期: 2011-01-01
卷: 47, 期:23, 页:6632-6634
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所; 湖南中医药大学; 先正达公司
英文摘要: The CF(3) radical was generated from the reaction of S-(trifluoromethyl)diphenylsulfonium triflate with Na(2)S(2)O(4) or HOCH(2)-SO(2)Na under suitable conditions without further reduction. Based on this, a method for the synthesis of alpha-trifluoromethylated ketones has been successfully developed.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/13710
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Zhang CP,Wang ZL,Chen QY,et al. Generation of the CF(3) radical from trifluoromethylsulfonium triflate and its trifluoromethylation of styrenes[J]. Chem. Commun.,2011,47(23):6632-6634.
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