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学科主题: 有机氟化学
题名: Thermal rearrangement of substituted difluoro(methylene)cyclopropane
其他题名: 取代的二氟(亚甲基)环丙烷在加热条件下的重排反应
作者: Hang XC(杭晓春) ; Gu WP(辜伟鹏) ; Chen QY(陈庆云) ; Xiao JC(肖吉昌) ; Xu WG(徐卫国) ; Liu SB(刘述斌)
通讯作者: 肖吉昌 ; 刘述斌
刊名: J. Fluor. Chem.
发表日期: 2011
卷: 132, 期:1, 页:63-67
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所; 浙江化工研究院; 北卡罗来纳大学
英文摘要: Both experimental and computational approaches have been employed in the present work to investigate the thermal conversion of substituted difluoro(methylene)cyclopropanes (F2MCP) E-1,1-difluoro-2,2-dimethyl-3-tosylmethylene cyclopropane 1, to the thermodynamically more stable F2MCP products, 1,1-difluoro-2-tosyl-3-(propan-2-ylidene)cyclopropane 2, and 1-(3-(difluoromethylene)-2,2-dimethylcyclopropylsulfonyl)-4-methylbenzen e 3. The X-ray crystal structure has been obtained for both 1 and 2, respectively, based on which theoretical analyses on their structure and stability have been carried out. Possible reaction mechanisms are proposed. (c) 2010 Elsevier B.V. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000286699400010
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/13706
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Hang XC,Gu WP,Chen QY,et al. Thermal rearrangement of substituted difluoro(methylene)cyclopropane[J]. J. Fluor. Chem.,2011,132(1):63-67.
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