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学科主题: 有机化学
题名: Electrophilic Reaction of Ag(III) N-Confused Porphyrin with Alcohols
其他题名: Ag(III)NCP与醇的亲电反应
作者: Jiang HW(蒋华卫) ; Hao F(郝菲) ; Chen QY(陈庆云) ; Xiao JC(肖吉昌) ; Liu SB(刘述斌) ; Gu YC(顾玉诚)
通讯作者: 肖吉昌
刊名: J. Org. Chem.
发表日期: 2010
卷: 75, 期:10, 页:3511-3514
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所; University of North Carolina; Syngenta
英文摘要: Experimental studies demonstrated that alcohols and amines can undergo a CF3COOAg-catalyzed nucleophilic addition at the outer C=N position of Ag(III) NCPs, leading to C-3-alkoxylated Ag(III) NCPs, which supports the computational result that the C=N bond on the periphery of Ag(III) NCPs is partially isolated from the 18 pi-electron macrocyclic conjugation system and is the active electrophilic center.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000277531200051
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/13696
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Jiang HW,Hao F,Chen QY,et al. Electrophilic Reaction of Ag(III) N-Confused Porphyrin with Alcohols[J]. J. Org. Chem.,2010,75(10):3511-3514.
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