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学科主题: 有机氟化学
题名: Reaction of difluorocarbene with propargyl esters and efficient synthesis of difluorocyclopropyl ketones
其他题名: 二氟卡宾和炔基酯的反应以及二氟环丙基酮的高效合成
作者: Hang XC(杭晓春) ; Gu WP(顾伟鹏) ; Chen QY(陈庆云) ; Xiao JC(肖吉昌)
通讯作者: 肖吉昌
刊名: Tetrahedron
发表日期: 2009
卷: 65, 期:32, 页:6320-6324
收录类别: SCI
部门归属: 上海有机所
英文摘要: Difluorocarbene generated from FSO2CF2CO2SiMe3 (TFDA) at 120 degrees C could reacted with terminal alkynes having an ester group at the a position to the triple bond. Difluorocyclopropenes were further converted to difluorocyclopropyl ketones under alkaline condition. Mechanism for the conversion was studied. (C) 2009 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000268736900005
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/13672
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Hang XC,Gu WP,Chen QY,et al. Reaction of difluorocarbene with propargyl esters and efficient synthesis of difluorocyclopropyl ketones[J]. Tetrahedron,2009,65(32):6320-6324.
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