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学科主题: 有机化学
题名: Practical and efficient synthesis of various meso-functionalized porphyrins via simple ligand-free nickel-catalyzed C-O, C-N, and C-C cross-coupling reactions
其他题名: 镍催化的meso-溴代卟啉的C-O,C-N和C-C偶联反应
作者: Liu C(刘超) ; Shen DM(沈冬梅) ; Chen QY(陈庆云)
通讯作者: 陈庆云
刊名: J. Org. Chem.
发表日期: 2007
卷: 72, 期:8, 页:2732-2736
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: Various meso-functionalized porphyrins were conveniently synthesized by direct reactions of meso-bromoporphyrins with oxygen-, nitrogen-, and carbon-based nucleophiles in moderate to high yields via practical, efficient, and ligand-free nickel-catalyzed C-O, C-N, and C-C bond-forming reactions. The central metal ions of the substrate porphyrin have much effect on the reactions. Introduction of Ni(II) as a central metal ion into the substrate porphyrin markedly accelerated the cross-coupling.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000245510600004
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/13648
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Liu C,Shen DM,Chen QY. Practical and efficient synthesis of various meso-functionalized porphyrins via simple ligand-free nickel-catalyzed C-O, C-N, and C-C cross-coupling reactions[J]. J. Org. Chem.,2007,72(8):2732-2736.
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