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学科主题: 有机氟化学
题名: Synthesis and reactions of 20 pi-electron beta-tetrakis(trifluoromethyl)-meso-tetraphenylporphyrins
其他题名: 20 π β-四(三氟甲基)-meso-四苯基卟啉的合成及反应
作者: Liu C(刘超) ; Shen DM(沈冬梅) ; Chen QY(陈庆云)
通讯作者: 陈庆云
刊名: J. Am. Chem. Soc.
发表日期: 2007
卷: 129, 期:18, 页:5814-5815
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: The 20 pi-electron nonaromatic isophlorin 2 had been successfully isolated and thoroughly characterized and was formed by reduction of Cu(II) beta-tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin (Cu1) with activated zinc powder. However, the reaction utilizing Ni(II) beta-tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin (Ni1) as a substrate and Na2S2O4 as a reductant at 100 degrees C resulted in the formation of a porphydimethene 5. Subsequent N-methylation of the isophlorin 2 led to N-dimethylated isophlorin 3 or N-tetramethylated isophlorin 4 depending on the choice of the base used.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000246180200015
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/13646
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Liu C,Shen DM,Chen QY. Synthesis and reactions of 20 pi-electron beta-tetrakis(trifluoromethyl)-meso-tetraphenylporphyrins[J]. J. Am. Chem. Soc.,2007,129(18):5814-5815.
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