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学科主题: 有机氟化学
题名: Fluoroalkylation of porphyrins: Preparation and characterization of meso- and β-fluoroalkyl-5,15-diarylporphyrins
其他题名: 卟啉氟烷基化: 各种meso-和β-位多氟烷基化卟啉的合成与表征
作者: Jin LM(金利美) ; Chen L(陈亮) ; Yin JJ(尹娟娟) ; Guo CC(郭灿城) ; Chen QY(陈庆云)
通讯作者: 郭灿城 ; 陈庆云
刊名: J. Fluor. Chem.
发表日期: 2005-01-01
卷: 126, 期:9-10, 页:1321-1326
收录类别: SCI
部门归属: 上海有机化学研究所元素有机化学研究室
英文摘要: Treatment of zinc(II) 5,15-diphenylporphyrin or free-base 5,15-diphenylporphyrin with 1.1 eq. of fluoroalkyl iodides (RfI) in the presence of 1.1 eq. Na2S2O4 in a mixture solvent of DMSO/THF at 45 ℃ for 1–2 h gave 2-fluoroalkyl-5,15-diphenylporphyrin and 5-fluoroalkyl- 10,20-diphenylporphyrin in a ratio from 1/3 to 1/8 in almost 50% total yields. The 5-fluoroalkyl-10,20-diphenylporphyrins were further fluoroalkylated to yield bis-fluoroalkylporphyrins.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/13608
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Jin LM,Chen L,Yin JJ,et al. Fluoroalkylation of porphyrins: Preparation and characterization of meso- and β-fluoroalkyl-5,15-diarylporphyrins[J]. J. Fluor. Chem.,2005,126(9-10):1321-1326.
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