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学科主题: 有机化学
题名: A facile and potent synthesis of meso,meso-linked porphyrin arrays using iodine(III) reagents
其他题名: 用三价碘试剂方便地合成各种meso,meso-连接的卟啉
作者: Jin LM(金利美) ; Chen L(陈亮) ; Yin JJ(尹娟娟) ; Guo CC(郭灿城) ; Chen QY(陈庆云)
通讯作者: 郭灿城 ; 陈庆云
刊名: Eur. J. Org. Chem.
发表日期: 2005
期: 18, 页:3994-4001
收录类别: SCI
部门归属: 湖南大学; 中科院上海应用物理研究所; 中科院上海有机化学研究所元素有机化学研究室
英文摘要: The synthesis of meso,meso-linked fluoroalkylporphyrin arrays has been accomplished, in excellent yields, by the simple treatment of a CHCL3 solution of zincated 5-fluoroalkyl10,20-diarylporphyrins (where fluoroalkyl = CF3, ClC2F4, n=ClC4F8, n-C6F13, etc.) with iodine(III) reagents such as PhI(OCO-CF3)(2) (PIFA, also named as bis(trifluoroacetoxy)iodolbenzene) or PhI(OAc)(2) (PIDA), For nonfluorinated zincated 5-substituted-10 20-diarylporphyrins (where substituent = phenyl, 4-methoxyphenyl, 4-methylphenyl, etc.) the similar Coupling reactions also proceed fast and (quantitatively. Moreover, various 15-unsubstituted metalloporphyrins Can also be coupled in high yields. (c) Wiley-WCH Verlagh GmbH & Co, KGaA, 69451 Weinheim, Germany, 2005.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000232068100016
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/13586
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Jin LM,Chen L,Yin JJ,et al. A facile and potent synthesis of meso,meso-linked porphyrin arrays using iodine(III) reagents[J]. Eur. J. Org. Chem.,2005(18):3994-4001.
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