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学科主题: 有机氟化学
题名: Synthesis of fluorinated indolizines and 4H-pyrrolo[1,2-α]benzimidazoles via 1,3-Dipolar cycloaddition of fluoroalkenes to N-Ylides
其他题名: 含氟烯烃与氮叶立德的1,3-偶极环加成反应来合成含氟中氮茚及4氢-吡咯并[1,2-α]苯并咪唑
作者: Wu K(吴恺) ; Chen QY(陈庆云)
通讯作者: 陈庆云
刊名: Synthesis
发表日期: 2003-01-01
期: 1, 页:35-40
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所氟有机化学开放实验室
英文摘要: In The presence of K^2CO^3 and Et^3N, pyridinium, quinolinium, isoquinolinium and benzimidazolinium N-ylides, generated in situ from their halides, react with gaseous flouroalkenes [CF^2=CFX(1),X=Cl(a), Br (b), CF^3(d) in DMF under atmospheric pressure in normal glassware at ℃ to give the corresonding fluorinated indolizines or H-pyrrolo[1,2-α]benzimidazoles via 1,3-dipolar [3+2] cycloaddition. Similar results are obtained with tetrafluoroethene in an autoclave.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/13568
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Wu K,Chen QY. Synthesis of fluorinated indolizines and 4H-pyrrolo[1,2-α]benzimidazoles via 1,3-Dipolar cycloaddition of fluoroalkenes to N-Ylides[J]. Synthesis,2003(1):35-40.
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