SIOC OpenIR  > 物理有机化学研究室
Vesicle Self-Assembly by Tetrathiafulvalene Derivatives in Both Polar and Nonpolar Solvents and Pseudo-Rotaxane Mediated Vesicle-to-Microtube Transformation
其他题名四硫富瓦烯衍生物在高、低极性溶剂中组装形成囊泡以及拟轮烷诱导的囊泡-纳米管转化
Zhang KD(章康达); Wang GT(王贵涛); Zhao X(赵新); Jiang XK(蒋锡夔); Li ZT(黎占亭)
2010
发表期刊Langmuir
ISSN0743-7463
卷号26期号:10页码:6878-6882
摘要This paper reports the self-assemblies of vesicles from two tetra thia fulvalene (TTF) derivatives (T1 and T2), that bear four or two amphiphilic side chains, in both polar and nonpolar solvents. The formation of vesicles is evidenced by scanning electron microscopy (SEM), atomic force microscopy (A FM), transmission electron microscopy (TEM), and dynamic light scattering (DLS) experiments, while the microstructaral aspects of the vesicles are investigated by UV-vis, H-1 , and high resolution TEM, which support a monolayer model for the vesicles. It is revealed that the formation of vesicles is driven by the combination of multiple noncovalent interactions, including, pi-pi stacking, hydrogen-bonding, van der Waals force, and S center dot center dot center dot S interactions. It is also found that, in the presence of electron-deficient cyclobis(paraquat-p-phenylene) tetracation cyclophane, vesicles of T2 can transform into microtubes as a result of the formation of the pseudo[2]rotaxane between the TTF unit of T2 and the cyclophane. This process can be reversed by introducing pristine TTF into the solution of microtubes, due to release of T2 from the pseudo[2]rotaxane through the formation of a more stable complex between pristine TTF, and tetracation cyclophane.
学科领域物理有机化学
部门归属中国科学院上海有机化学研究所
URL查看原文
收录类别SCI
语种英语
WOS记录号WOS:000277398600004
引用统计
被引频次:24[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/12764
专题物理有机化学研究室
通讯作者Zhao X(赵新); Li ZT(黎占亭)
推荐引用方式
GB/T 7714
Zhang KD,Wang GT,Zhao X,et al. Vesicle Self-Assembly by Tetrathiafulvalene Derivatives in Both Polar and Nonpolar Solvents and Pseudo-Rotaxane Mediated Vesicle-to-Microtube Transformation[J]. Langmuir,2010,26(10):6878-6882.
APA 章康达,王贵涛,赵新,蒋锡夔,&黎占亭.(2010).Vesicle Self-Assembly by Tetrathiafulvalene Derivatives in Both Polar and Nonpolar Solvents and Pseudo-Rotaxane Mediated Vesicle-to-Microtube Transformation.Langmuir,26(10),6878-6882.
MLA 章康达,et al."Vesicle Self-Assembly by Tetrathiafulvalene Derivatives in Both Polar and Nonpolar Solvents and Pseudo-Rotaxane Mediated Vesicle-to-Microtube Transformation".Langmuir 26.10(2010):6878-6882.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
2010289.pdf(2231KB) 开放获取--请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[章康达]的文章
[王贵涛]的文章
[赵新]的文章
百度学术
百度学术中相似的文章
[章康达]的文章
[王贵涛]的文章
[赵新]的文章
必应学术
必应学术中相似的文章
[章康达]的文章
[王贵涛]的文章
[赵新]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。