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Self-Assembly of Vesicles from Amphiphilic Aromatic Amide-Based Oligomers
其他题名基于两亲性寡聚芳酰胺的囊泡自组装
Xu YX(徐云祥); Wang GT(王贵涛); Zhao X(赵新); Jiang XK(蒋锡夔); Li ZT(黎占亭)
2009
发表期刊Langmuir
ISSN0743-7463
卷号25期号:5页码:2684-2688
摘要A novel class of linear arylamide oligomers has been designed and synthesized from naphthalene-2,7-diamine and benzene-1,3,5-tricarboxylic acid segments. The molecules carry two (tert-butoxycarbonylamino) groups at the ends and one to three hydrophilic N,N-bis(2-(2-(2-methoxyethoxy)ethoxy)ethyl)amino groups at one side of the backbone. The oligomers self-assembled into vesicular structures in methanol as a result of ordered stacking of the oligomeric amide backbones, which were evidenced by SEM, AFM, TEM, and fluorescent micrography experiments. It was also found that the tert-butoxycarbonylamino groups at the ends played an important role in promoting the ordered stacking of the backbones. Structural factors that affected the self-assembly of the oligomers were investigated. A two-layer model that was supported by TEM has been proposed for the formation of the vesicular structures, which was driven by both the hydrogen bonding and aromatic stacking.
学科领域物理有机化学
部门归属上海有机所
URL查看原文
收录类别SCI
语种英语
WOS记录号WOS:000263770800025
引用统计
被引频次:41[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/12742
专题物理有机化学研究室
通讯作者Zhao X(赵新); Li ZT(黎占亭)
推荐引用方式
GB/T 7714
Xu YX,Wang GT,Zhao X,et al. Self-Assembly of Vesicles from Amphiphilic Aromatic Amide-Based Oligomers[J]. Langmuir,2009,25(5):2684-2688.
APA 徐云祥,王贵涛,赵新,蒋锡夔,&黎占亭.(2009).Self-Assembly of Vesicles from Amphiphilic Aromatic Amide-Based Oligomers.Langmuir,25(5),2684-2688.
MLA 徐云祥,et al."Self-Assembly of Vesicles from Amphiphilic Aromatic Amide-Based Oligomers".Langmuir 25.5(2009):2684-2688.
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