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Self-assembly of a novel series of hetero-duplexes driven by donor-acceptor interaction oligo(glycol)
其他题名协同供体-受体相互作用驱动的缠绕型异体二聚体
Zhou QZ(周其忠); Jia MX(贾木欣); Shao XB(邵学斌); Wu LZ(吴骊珠); Jiang XK(蒋锡夔); Li ZT(黎占亭); Chen GJ(陈光巨)
2005
发表期刊Tetrahedron
ISSN0040-4020
卷号61期号:30页码:7117-7124
摘要The self-assembly of a novel series of donor-acceptor interaction-driven artificial hetero-duplexes in organic media has been described. Four linear compounds 1a-1d, bearing two to five electron rich 1,5-dioxynaphthalene units connected by the tetra(ethylene glycol) linker, respectively, have been prepared and used as donors, while eight compounds 2a-2d, 13-16, bearing one to four electron deficient pyromellitic diimide, 1,4,5,8-naphthalene-tetracarboxydiimide, or perylene-3,4,9,10-tetracarboxydiimide units, respectively, have been used as acceptors. The structure of the hetero-duplexes has been characterized by the H-1 NMR, UV-vis spectroscopy and vapor pressure osmometry. It is revealed that the binding stability of the duplexes vary greatly, depending on the length and structure of the monomers and also the solvent, and hetero-duplex 1d(.)2d displays a maximum association constant of ca. 1.0 x 10(4) m(-1) in chloroform. (c) 2005 Elsevier Ltd. All rights reserved.
学科领域物理有机化学
部门归属中科学院上海有机化学研究所; 北京师范大学; 中科院北京理化所
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收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/12682
专题物理有机化学研究室
通讯作者Li ZT(黎占亭); Chen GJ(陈光巨)
推荐引用方式
GB/T 7714
Zhou QZ,Jia MX,Shao XB,et al. Self-assembly of a novel series of hetero-duplexes driven by donor-acceptor interaction oligo(glycol)[J]. Tetrahedron,2005,61(30):7117-7124.
APA 周其忠.,贾木欣.,邵学斌.,吴骊珠.,蒋锡夔.,...&陈光巨.(2005).Self-assembly of a novel series of hetero-duplexes driven by donor-acceptor interaction oligo(glycol).Tetrahedron,61(30),7117-7124.
MLA 周其忠,et al."Self-assembly of a novel series of hetero-duplexes driven by donor-acceptor interaction oligo(glycol)".Tetrahedron 61.30(2005):7117-7124.
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