中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 物理有机化学研究室  > 期刊论文
学科主题: 物理有机化学
题名: A general approach to L-tyrosine porphyrins
其他题名: 一种合成酪氨酸卟啉的通用方法
作者: Chen H(陈红) ; Shao XB(邵学斌) ; Jiang XK(蒋锡夔)
通讯作者: 蒋锡夔
刊名: Tetrahedron
发表日期: 2003-01-01
卷: 59, 期:19, 页:3505-3510
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所物理有机化学实验室
英文摘要: A novel and general approach has been developed to prepare L-tyrosine-containing porphyrins. The key intermediates. 2-lert-butoxycarbonylamino-3-(3-formyl-4-hexyloxy-phenyl)-propionic acid hexyl ester and 2-tert-butoxycarbonylamino-3-(3-formyl-4-meth-oxy-phenyl)-propionic acid methyl ester. Were prepared by the Reimer-Tiemann reaction ot Boc-protected L-tyrosine. Which was followed by esterification and alkylation of the phenol hydroxide. A number ot novel chiral L-tyrosine porphyrins were obtained from the reactions of 2-tert-butoxycarbonylamino-3-(3-formy]-4-alkoxy-phenyl)-propionic acid ester with different dipyuolylmethanes and the reaction of 5-(4-trifiuoromethylphenyl)pynomethane aHorded the highest yield. The tyrosine porphyrins could be readily deprotected lo afford the corresponding diacid or diamine derivatives.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/12642
Appears in Collections:物理有机化学研究室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2003208.pdf(211KB)----开放获取--View Download

Recommended Citation:
Chen H,Shao XB,Jiang XK. A general approach to L-tyrosine porphyrins[J]. Tetrahedron,2003,59(19):3505-3510.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[陈红]'s Articles
[邵学斌]'s Articles
[蒋锡夔]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[陈红]‘s Articles
[邵学斌]‘s Articles
[蒋锡夔]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2003208.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace