中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Development of a General and Practical Iron Nitrate/TEMPO-Catalyzed Aerobic Oxidation of Alcohols to Aldehydes/Ketones: Catalysis with Table Salt
其他题名: 发展一种通用、易操作的硝酸铁、TEMPO和食盐共催化的醇到醛/酮的空气氧化反应
作者: Ma SM(麻生明) ; Liu JX(刘金仙) ; Li SH(李苏华) ; Chen B(陈波) ; Cheng JJ(成佳佳) ; Kuang JQ(况锦强) ; Liu Y(刘宇) ; Wan BQ(万保强) ; Wang YL(王玉立) ; Ye JT(叶俊涛) ; Yu Q(俞琼) ; Yuan WM(袁伟明) ; Yu SC(余世超)
通讯作者: 麻生明
刊名: Adv. Synth. Catal.
发表日期: 2011
卷: 353, 期:6, 页:1005-1017
收录类别: SCI
部门归属: 华东师范大学; 中科院上海有机化学研究所
英文摘要: Oxidation of alcohols is a fundamental transformation related to our daily life. Traditional approaches with at least one stoichiometric amount of oxidants are expensive and cause serious environmental burdens. There are many reports on the aerobic oxidation of simple alcohols such as alkyl or phenyl carbinols and allylic alcohols, which used oxygen or air as the environmentally benign oxidant forming water as the only by-product. However, no such protocol has been reported for allenols and propargylic alcohols. Thus, it still highly desirable to develop efficient room temperature oxidations of alcohols with a wide scope including allenols and propargylic alcohols. In this paper, an efficient and clean aerobic oxidation of so far the widest spectrum of alcohols using 1 atm of oxygen or air, producing aldehydes/ketones at room temperature in fairly high isolated yields mostly within a couple of hours is described. It is interesting to observe that the reaction has been efficiently expedited by a catalytic amount of sodium chloride in easily recoverable 1,2-dichloroethane. A mechanism involving NO and NO(2) has been proposed based on the results of the control experiments and GC-MS studies of the in-situ formed gas phase of the reaction mixture.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000290613800028
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/12234
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2011227.pdf(317KB)----开放获取--View Download

Recommended Citation:
Ma SM,Liu JX,Li SH,et al. Development of a General and Practical Iron Nitrate/TEMPO-Catalyzed Aerobic Oxidation of Alcohols to Aldehydes/Ketones: Catalysis with Table Salt[J]. Adv. Synth. Catal.,2011,353(6):1005-1017.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[麻生明]'s Articles
[刘金仙]'s Articles
[李苏华]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[麻生明]‘s Articles
[刘金仙]‘s Articles
[李苏华]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2011227.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace