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学科主题: 金属有机化学
题名: Catalyst-Controlled Ring-Opening Cycloisomerization Reactions of Cyclopropenyl Carboxylates for Highly Regioselective Synthesis of Different 2-Alkoxyfurans
其他题名: 通过催化剂控制的环丙烯羧酸酯的开环异构化来构建不同的2-烷氧基呋喃类化合物的反应
作者: Chen J(陈洁) ; Ma SM(麻生明)
通讯作者: 麻生明
刊名: Chem.-Asian J.
发表日期: 2010
卷: 5, 期:11, 页:2415-2421
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所; 华东师范大学
英文摘要: Differently substituted 2-alkoxyfurans (2,3,4- or 2,3,5-trisubstituted furans) were highly regioselectively synthesized by means of the ring-opening cycloisomerization of the same cyclopropenyl carboxylates with good yields in different solvents and excellent regioselectivity by using [Cu(acac)(2)] (acac=acetylacetonate) or [RuCl2(PPh3)(3)] as the catalyst, respectively. The structures of these two different types of furans were established by X-ray diffraction studies. A rationale has been proposed.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000284515100014
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/12224
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Chen J,Ma SM. Catalyst-Controlled Ring-Opening Cycloisomerization Reactions of Cyclopropenyl Carboxylates for Highly Regioselective Synthesis of Different 2-Alkoxyfurans[J]. Chem.-Asian J.,2010,5(11):2415-2421.
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