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Catalyst-Controlled Ring-Opening Cycloisomerization Reactions of Cyclopropenyl Carboxylates for Highly Regioselective Synthesis of Different 2-Alkoxyfurans
其他题名通过催化剂控制的环丙烯羧酸酯的开环异构化来构建不同的2-烷氧基呋喃类化合物的反应
Chen J(陈洁); Ma SM(麻生明)
2010
发表期刊Chem.-Asian J.
ISSN1861-4728
卷号5期号:11页码:2415-2421
摘要Differently substituted 2-alkoxyfurans (2,3,4- or 2,3,5-trisubstituted furans) were highly regioselectively synthesized by means of the ring-opening cycloisomerization of the same cyclopropenyl carboxylates with good yields in different solvents and excellent regioselectivity by using [Cu(acac)(2)] (acac=acetylacetonate) or [RuCl2(PPh3)(3)] as the catalyst, respectively. The structures of these two different types of furans were established by X-ray diffraction studies. A rationale has been proposed.
学科领域金属有机化学
部门归属中国科学院上海有机化学研究所; 华东师范大学
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收录类别SCI
语种英语
WOS记录号WOS:000284515100014
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文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/12224
专题金属有机化学国家重点实验室
通讯作者Ma SM(麻生明)
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GB/T 7714
Chen J,Ma SM. Catalyst-Controlled Ring-Opening Cycloisomerization Reactions of Cyclopropenyl Carboxylates for Highly Regioselective Synthesis of Different 2-Alkoxyfurans[J]. Chem.-Asian J.,2010,5(11):2415-2421.
APA 陈洁,&麻生明.(2010).Catalyst-Controlled Ring-Opening Cycloisomerization Reactions of Cyclopropenyl Carboxylates for Highly Regioselective Synthesis of Different 2-Alkoxyfurans.Chem.-Asian J.,5(11),2415-2421.
MLA 陈洁,et al."Catalyst-Controlled Ring-Opening Cycloisomerization Reactions of Cyclopropenyl Carboxylates for Highly Regioselective Synthesis of Different 2-Alkoxyfurans".Chem.-Asian J. 5.11(2010):2415-2421.
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