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学科主题: 有机化学
题名: An efficient approach for monofluorination via highly regioselective fluorohydroxylation reaction of 3-aryl-1,2-allenes with selectfluor
其他题名: An efficient approach for monofluorination via highly regioselective fluorohydroxylation reaction of 3-aryl-1,2-allenes with selectfluor
作者: Zhou C(周超) ; Li J(李晶) ; Lv B(吕博) ; Fu CL(傅春玲) ; Ma SM(麻生明)
通讯作者: 傅春玲 ; 麻生明
刊名: Org. Lett.
发表日期: 2008
卷: 10, 期:4, 页:581-583
收录类别: SCI
部门归属: 浙江大学; 上海有机所
英文摘要: The internal C-C double bond in 3-aryl-1,2-allenes was highly regioselectively fluorohydroxylated to afford 2-fluoroalken-3-ols in 37-88% yields by using Selectfluor as the electrophilic reagent. The regioselectivity may be determined by the electronic effect, while the reactivity may be controlled by the stabilization effect of the aryl group in the allylic cationic intermediates.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000252989500015
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/12176
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Zhou C,Li J,Lv B,et al. An efficient approach for monofluorination via highly regioselective fluorohydroxylation reaction of 3-aryl-1,2-allenes with selectfluor[J]. Org. Lett.,2008,10(4):581-583.
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