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Controllable Cycilization Reactions of 2-(2 ',3 '-Allenyl)acetylacetates Catalyzed by Gold and Palladium Affording Substituted Cyclopentene and 4,5-Dihydrofuran Derivatives with Distinct Selectivity
其他题名Controllable Cycilization Reactions of 2-(2',3'-Allenyl)acetylacetates Catalyzed by Gold and Palladium Affording Substituted Cyclopentene and 4,5-Dihydrofuran Derivatives with Distinct Selectivity
Jiang XF(姜雪峰); Ma XJ(马晓婧); Zheng ZL(郑子龙); Ma SM(麻生明)
2008
发表期刊Chem.-Eur. J.
ISSN0947-6539
卷号14期号:28页码:8572-8578
摘要Efficient room-temperature syntheses of cyclopentenes and 4,5-dihydrofurans with different substitution patterns were performed starting from the same materials (i.e., 2-(2',3'-allenyl)acetyl acetates). Depending on the choice of metal catalyst, the Au-catalyzed reaction afforded C-attack-5-endo cyclization products 2, whereas the Pd-catalyzed one led to the formation of O-attack-5-exo cyclization products 3. The selectivity may be explained by the steric and electronic effects of the substrates and catalysts.
学科领域金属有机化学
部门归属上海有机所; 华东师范大学
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收录类别SCI
语种英语
WOS记录号WOS:000260035900019
引用统计
被引频次:34[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/12148
专题金属有机化学国家重点实验室
通讯作者Ma SM(麻生明)
推荐引用方式
GB/T 7714
Jiang XF,Ma XJ,Zheng ZL,et al. Controllable Cycilization Reactions of 2-(2 ',3 '-Allenyl)acetylacetates Catalyzed by Gold and Palladium Affording Substituted Cyclopentene and 4,5-Dihydrofuran Derivatives with Distinct Selectivity[J]. Chem.-Eur. J.,2008,14(28):8572-8578.
APA 姜雪峰,马晓婧,郑子龙,&麻生明.(2008).Controllable Cycilization Reactions of 2-(2 ',3 '-Allenyl)acetylacetates Catalyzed by Gold and Palladium Affording Substituted Cyclopentene and 4,5-Dihydrofuran Derivatives with Distinct Selectivity.Chem.-Eur. J.,14(28),8572-8578.
MLA 姜雪峰,et al."Controllable Cycilization Reactions of 2-(2 ',3 '-Allenyl)acetylacetates Catalyzed by Gold and Palladium Affording Substituted Cyclopentene and 4,5-Dihydrofuran Derivatives with Distinct Selectivity".Chem.-Eur. J. 14.28(2008):8572-8578.
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