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Rh-I-catalyzed bimolecular cyclization between two different 1,5-bisallenes: A combinatorial one-step approach to heterosteroids and mechanistic implications
其他题名Rh-I-catalyzed bimolecular cyclization between two different 1,5-bisallenes: A combinatorial one-step approach to heterosteroids and mechanistic implications
Ma SM(麻生明); Lu LH(陆梁华)
2007
发表期刊Chem.-Asian J.
ISSN1861-4728
卷号2期号:1页码:199-204
摘要In this paper, a bimolecular-cyclization reaction between two different bis(allene)s with at least one heteroatom as the tether under the catalysis of trans-[RhCl(CO)(PPh3)(2)] is described. This protocol provides an efficient entry to different heterocyclic 18.19-norsteroid-like scaffolds. The tri-cyclic product was formed highly selectively from the cyclization reaction of bis (2,3-butadienyl) sulfide with dimeth- yl 2-bis(2',3'-butadienyl)malonate, which sheds light on the mechanism involving the metalla-[4.3.0]-bicyclic intermediate formed by the cyclometallation of the terminal and the internal C=C bonds of each of the two allene moieties in 2-bis(2',3'-butadienyl)malonate.
学科领域金属有机化学
部门归属上海有机所
URL查看原文
收录类别SCI
语种英语
WOS记录号WOS:000243518900019
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被引频次:19[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/12124
专题金属有机化学国家重点实验室
通讯作者Ma SM(麻生明)
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GB/T 7714
Ma SM,Lu LH. Rh-I-catalyzed bimolecular cyclization between two different 1,5-bisallenes: A combinatorial one-step approach to heterosteroids and mechanistic implications[J]. Chem.-Asian J.,2007,2(1):199-204.
APA 麻生明,&陆梁华.(2007).Rh-I-catalyzed bimolecular cyclization between two different 1,5-bisallenes: A combinatorial one-step approach to heterosteroids and mechanistic implications.Chem.-Asian J.,2(1),199-204.
MLA 麻生明,et al."Rh-I-catalyzed bimolecular cyclization between two different 1,5-bisallenes: A combinatorial one-step approach to heterosteroids and mechanistic implications".Chem.-Asian J. 2.1(2007):199-204.
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