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学科主题: 有机化学
题名: An efficient synthesis of 4-halo-5-hydroxyfuran-2(5H)-ones via the sequential halolactonization and gamma-hydroxylation of 4-aryl-2,3-alkadienoic acids
其他题名: 4-芳基-2,3-联烯酸的卤代环化及-羟基化合成4-卤代-5-羟基-2(5H)-呋喃酮
作者: Ma SM(麻生明) ; Wu B(吴滨) ; Shi ZJ(施章杰)
通讯作者: 麻生明
刊名: J. Org. Chem.
发表日期: 2004
卷: 69, 期:4, 页:1429-1431
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所有机金属化学实验室
英文摘要: 4-Halo-5-hydroxyfuran-2(5H)-ones were synthesized via the efficient sequential halolactonization-hydroxylation reaction of 4-aryl-2,3-allenoic acids with 12 or CuX2 (X = Br or Cl) in moderate to good yields. The structures of the products were established by the X-ray single-crystal diffraction study of 3-methyl-4-iodo-5-phenyl-5-hydroxyl-2(5H)-furanone (2a). A rationale for this reaction was discussed based on some brief mechanistic study.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000188955400066
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/11984
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Ma SM,Wu B,Shi ZJ. An efficient synthesis of 4-halo-5-hydroxyfuran-2(5H)-ones via the sequential halolactonization and gamma-hydroxylation of 4-aryl-2,3-alkadienoic acids[J]. J. Org. Chem.,2004,69(4):1429-1431.
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