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学科主题: 金属有机化学
题名: Ru催化的C-H键的活化反应
其他题名: Activation reactions of Ru-catalyzed arylic or olefinic C-H bonds
作者: 余世超 ; 麻生明
通讯作者: 麻生明
刊名: 有机化学
发表日期: 2002-01-01
卷: 22, 期:5, 页:307-317
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
摘要: 概述了Ru催化的碳氢键的活化反应, 包括C-H烯烃, C-H 炔烃和 C-H/CO/烯烃偶联反应, 加氢酰化反应, 硅化反应.
英文摘要: In the last few years, much has been learned about the transition metal-catalyzed activation of arylic or olefinic C-H bonds. An imjportant extension of these reactions such as C-H/olefin, C-H/acetylene, C-H/CO and C-H/CO/olefin couplings, hydroacylation and silylation can be regarded as practical tools, for these reactions exhibit high selectivity, high efficiency and wide applicability. Especially the C-H/CO/olefin coupling protocol can be a useful complementary method to Friedel-Crafts reaction, since it takes place even when there're electron-withdrawing groups in the aryl groups of substrates. In these reactions the coordination of the substrates to the ruthenium center in the catalyst complex is a necessary prerequisite for the reactions to proceed. In this paper, we'll survey the Ru-catalyzed functionalizaions of C-H bonds that were published up to the end of 2000. These catalytic reactions involve a step of nucleophilic addition by a ruthenium complex. The factors affecting the selectivity shown by different catalysts are also discussed.
语种: 中文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/11902
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
余世超,麻生明. Ru催化的C-H键的活化反应[J]. 有机化学,2002,22(5):307-317.
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