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学科主题: 金属有机化学
题名: Synthesis of (+) or (-)-2-(8'-Diphenylphosphino-1'-naphthyl) oxazoline ligands and their application in Pd-catalyzed allylic alkylation reaction
其他题名: (+)or (-)-2-(8'1二苯基膦基萘-1'-)噁唑啉合成及在钯催化烯丙基烷基化反应中的应用
作者: Ma SM(麻生明) ; Duan DH(段德慧)
通讯作者: 麻生明
刊名: Chin. J. Chem.
发表日期: 2002-01-01
卷: 20, 期:11, 页:1363-1368
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: We synthesized optically active 2-(8'-diphenylphosphino-1'-naphthyl) oxazoline ligands by palladium-catalyzed coupling reactions of (trimethylsilyl) diphenylphosphine with 2-(8'-bromo1'-naphthyl)oxazolines, which, in turn, were prepared from 8-bromo-1-naphthoyl chloride by the reaction with natural optical active amino aleohols. Pd-catalyzed allylic alkylation reaction induced by these chiral ligands gave the allylic substiuted products in high yields and moderate ee values.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/11896
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Ma SM,Duan DH. Synthesis of (+) or (-)-2-(8'-Diphenylphosphino-1'-naphthyl) oxazoline ligands and their application in Pd-catalyzed allylic alkylation reaction[J]. Chin. J. Chem.,2002,20(11):1363-1368.
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