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学科主题: 有机化学
题名: Highly selective hydrohalogenation reaction of substituted 2,3-allenoates
其他题名: 2,3-联烯酸酯的高选择性氢卤化反应
作者: Ma SM(麻生明) ; Wang GW(王光伟)
通讯作者: 麻生明
刊名: Chin. J. Chem.
发表日期: 1999
卷: 17, 期:5, 页:545-549
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: The hydrohalogenation reaction of 1-alkyl substituted 1,2-allenyl carboxylic acid esters (1) with MX (M=Na, or Li, X=Cl, Br, I) afforded a mixture of β,γ-unsaturated 3-halo-3-alkenoates (2) and α,β-unsaturated 3-halo-2-alkenoates (3) in HOAc, while using a mixture of HOAc-CF=3CO=2H (1:1) or CF=3CO=2H as thereaction medium the corresponding reaction cleanly produced β, γ-unstaturated 3-halo-3-alkenoates (2) as the sole products in high yields. The subsequent coupling reactions were studied.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000083814600016
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/11788
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Ma SM,Wang GW. Highly selective hydrohalogenation reaction of substituted 2,3-allenoates[J]. Chin. J. Chem.,1999,17(5):545-549.
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