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Synthesis of β-halobutenolides and their Pd(0)-catalyzed cross-coupling reactions with terminal alkynes and organozine reagents. A general route to β-substituted butenolides and formal synthesis of cis-whisky lactone
其他题名β-卤代丁烯酸内酯的合成及其与末端炔烃和有机锌试剂的 P(0)-催化偶联反应。Β-卤代丁烯酸内酯的通用合成方法及cis-Whishky lactone 的表观合成
Ma SM(麻生明); Shi ZJ(施章杰); Yu ZQ(俞瞻前)
1999
发表期刊Tetrahedron
ISSN0040-4020
卷号55页码:12137-12148
摘要An improved procedure for the effcient synthesis of β-halobutenolides wasdeveloped. The Pd(0)-catalyzed coupling reactions of β-halobutenolides with terminal alkynes or organozinc reagents, I.e., 1-alkenyl, aryl, and alkyl zinc reagents, to afford β-substituted dutenolides were carefully studied. Using the coupling protocol ofγ-(n-butyl)β-iodobutenolide with methylzinc halide, we performed an efficient formal synthesis of whisky lactone.
学科领域有机化学
部门归属中国科学院上海有机化学研究所金属有机化学开放实验室
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收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/11786
专题金属有机化学国家重点实验室
通讯作者Ma SM(麻生明)
推荐引用方式
GB/T 7714
Ma SM,Shi ZJ,Yu ZQ. Synthesis of β-halobutenolides and their Pd(0)-catalyzed cross-coupling reactions with terminal alkynes and organozine reagents. A general route to β-substituted butenolides and formal synthesis of cis-whisky lactone[J]. Tetrahedron,1999,55:12137-12148.
APA 麻生明,施章杰,&俞瞻前.(1999).Synthesis of β-halobutenolides and their Pd(0)-catalyzed cross-coupling reactions with terminal alkynes and organozine reagents. A general route to β-substituted butenolides and formal synthesis of cis-whisky lactone.Tetrahedron,55,12137-12148.
MLA 麻生明,et al."Synthesis of β-halobutenolides and their Pd(0)-catalyzed cross-coupling reactions with terminal alkynes and organozine reagents. A general route to β-substituted butenolides and formal synthesis of cis-whisky lactone".Tetrahedron 55(1999):12137-12148.
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