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学科主题: 有机化学
题名: Synthesis of β-halobutenolides and their Pd(0)-catalyzed cross-coupling reactions with terminal alkynes and organozine reagents. A general route to β-substituted butenolides and formal synthesis of cis-whisky lactone
其他题名: β-卤代丁烯酸内酯的合成及其与末端炔烃和有机锌试剂的 P(0)-催化偶联反应。Β-卤代丁烯酸内酯的通用合成方法及cis-Whishky lactone 的表观合成
作者: Ma SM(麻生明) ; Shi ZJ(施章杰) ; Yu ZQ(俞瞻前)
通讯作者: 麻生明
刊名: Tetrahedron
发表日期: 1999-01-01
卷: 55, 页:12137-12148
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: An improved procedure for the effcient synthesis of β-halobutenolides wasdeveloped. The Pd(0)-catalyzed coupling reactions of β-halobutenolides with terminal alkynes or organozinc reagents, I.e., 1-alkenyl, aryl, and alkyl zinc reagents, to afford β-substituted dutenolides were carefully studied. Using the coupling protocol ofγ-(n-butyl)β-iodobutenolide with methylzinc halide, we performed an efficient formal synthesis of whisky lactone.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/11786
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Ma SM,Shi ZJ,Yu ZQ. Synthesis of β-halobutenolides and their Pd(0)-catalyzed cross-coupling reactions with terminal alkynes and organozine reagents. A general route to β-substituted butenolides and formal synthesis of cis-whisky lactone[J]. Tetrahedron,1999,55:12137-12148.
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