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学科主题: 天然产物有机化学
题名: STUDIES ON STEROIDAL PLANT-GROWTH REGULATORS .33. NOVEL METHOD FOR CONSTRUCTION OF THE SIDE-CHAIN OF 23-ARYLBRASSINOSTEROIDS VIA HECK ARYLATION AND ASYMMETRIC DIHYDROXYLATION AS KEY STEPS
其他题名: STUDIES ON STEROIDAL PLANT-GROWTH REGULATORS .33. NOVEL METHOD FOR CONSTRUCTION OF THE SIDE-CHAIN OF 23-ARYLBRASSINOSTEROIDS VIA HECK ARYLATION AND ASYMMETRIC DIHYDROXYLATION AS KEY STEPS
作者: Huang LF(黄良富) ; Zhou WS(周维善)
通讯作者: 周维善
刊名: J. Chem. Soc.-Perkin Trans. 1
发表日期: 1994-01-01
期: 24, 页:3579-3585
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: An efficient method for construction of the 23-arylbrassinosteroidal side-chain is described via Heck coupling and asymmetric osmylation as key steps. Several new (22R,23R)-23-arylbrassinosteroids were synthesized. The overall yields of 23-phenylbrassinosteroid 18 and the new compound 13a from 22-olefin 7 were 10% (seven steps) and 37% (five steps), respectively.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/11602
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Huang LF,Zhou WS. STUDIES ON STEROIDAL PLANT-GROWTH REGULATORS .33. NOVEL METHOD FOR CONSTRUCTION OF THE SIDE-CHAIN OF 23-ARYLBRASSINOSTEROIDS VIA HECK ARYLATION AND ASYMMETRIC DIHYDROXYLATION AS KEY STEPS[J]. J. Chem. Soc.-Perkin Trans. 1,1994(24):3579-3585.
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