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学科主题: 元素有机化学
题名: An enantio selective nucleophilic addition of alpha, beta-unsaturated trifluoromethylketones catalyzed by L-proline derivatives
其他题名: L-辅氨酸衍生物催化的α,β-不饱和三氟甲基酮的对映选择亲核加成反应
作者: Zhang DH(张德晖) ; Yuan CY(袁承业)
刊名: Tetrahedron
发表日期: 2008
卷: 64, 期:10, 页:2480-2488
收录类别: SCI
部门归属: 上海有机所
英文摘要: An unexpected enantioselective 1,2-aldol reaction of acetone with alpha, beta-unsaturated trifluoromethylketone catalyzed by L-proline derivative was described. The absolute configuration of the resulting chiral product was assigned based on a single crystal X-ray diffraction analysis. Structure-reactivity study of this organocatalytic system was briefly discussed. A reaction mechanism was tentatively postulated. (C) 2007 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000253432600023
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/11076
Appears in Collections:上海有机化学研究所_期刊论文

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Recommended Citation:
Zhang DH,Yuan CY. An enantio selective nucleophilic addition of alpha, beta-unsaturated trifluoromethylketones catalyzed by L-proline derivatives[J]. Tetrahedron,2008,64(10):2480-2488.
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