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学科主题: 金属有机化学
题名: Catalytic Asymmetric Addition of Arylboronic Acids to Isatins using C(2)-Symmetric Cationic N-Heterocyclic Carbenes (NHCs) Pd(2+) Diaqua Complexes as Catalysts
其他题名: 手性氮杂环卡宾阳离子钯催化的芳基硼酸和Isatins的不对称加成反应
作者: Liu Z(刘震) ; Gu P(古彭) ; Shi M(施敏) ; MCDOWELL PATRICK ; Li GG(李桂根)
刊名: Org. Lett.
发表日期: 2011-01-01
卷: 13, 期:9, 页:2314-2317
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 美国德州理工大学
英文摘要: A catalytic asymmetric addition of arylboronic acids to isatins has been achieved by using chiral cationic C(2)-symmetric N-heterocyclic carbene (NHC) Pd(2+) cliaqua complexes as the catalysts. The reaction can be performed under convenient conditions to give the corresponding adducts in good to high yields (79-94%) and moderate to excellent enantioselectivities (up to 94% ee) in the presence of LiOAr as the promoter which was generated in situ.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/10418
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Liu Z,Gu P,Shi M,et al. Catalytic Asymmetric Addition of Arylboronic Acids to Isatins using C(2)-Symmetric Cationic N-Heterocyclic Carbenes (NHCs) Pd(2+) Diaqua Complexes as Catalysts[J]. Org. Lett.,2011,13(9):2314-2317.
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