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学科主题: 金属有机化学
题名: Ring-Opening Reaction of Vinylidenecyclopropanediesters Catalyzed by Re-2(CO)(10) or Yb(OTf)(3)
其他题名: 金属Re和Yb催化的亚乙烯基环丙烷的开环反应
作者: Wu L(吴蕾) ; Shi M(施敏)
刊名: Eur. J. Org. Chem.
发表日期: 2011
期: 6, 页:1099-1105
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: Ring-opening reaction of vinylidenecyclopropanediesters catalyzed by Re-2(CO)(10) or Yb(OTf)(3) afforded 2H-pyran-2-one derivatives or alpha,beta-unsaturated ketones in moderate to good yields through a highly regioselective carbon-carbon bond cleavage pathway. The substituents at the cyclopropane mainly determine the regioselectivity of the carbon-carbon bond cleavage, providing different products of tandem ring-opening and rearrangement reactions.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000287163700011
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/10414
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Wu L,Shi M. Ring-Opening Reaction of Vinylidenecyclopropanediesters Catalyzed by Re-2(CO)(10) or Yb(OTf)(3)[J]. Eur. J. Org. Chem.,2011(6):1099-1105.
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