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学科主题: 金属有机化学
题名: Ring-Opening Reaction of Methylenecyclopropanes Derived from Methylenecyclopropyl Aldehydes through Cope Rearrangement
其他题名: 从亚甲基环丙烷醛得到的亚甲基环丙烷的开环反应
作者: Tang XY(唐翔鹰) ; Wei Y(魏音) ; Shi M(施敏)
通讯作者: 魏音 ; 施敏
刊名: Eur. J. Org. Chem.
发表日期: 2010
期: 31, 页:6038-6042
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: Tandem Wittig reaction/Cope rearrangement of methylenecyclopropyl aldehydes 1 with cinnamyltriphenylphosphonium bromide afforded a convenient method for the synthesis of cyclopentene derivatives 2 in moderate yields in a one-pot manner. Dialkyl 2-[(2-methylenecyclopropyl)methylene]malonates 3 derived from methylenecyclopropyl aldehydes 1 could produce two kinds of cyclopentene derivatives, 4 and 5, in good total yields through a thermally induced Cope rearrangement upon heating at 100 degrees C. Plausible reaction mechanisms are discussed on the basis of previous reports and on control experiments.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000284515800014
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/10400
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Tang XY,Wei Y,Shi M. Ring-Opening Reaction of Methylenecyclopropanes Derived from Methylenecyclopropyl Aldehydes through Cope Rearrangement[J]. Eur. J. Org. Chem.,2010(31):6038-6042.
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