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学科主题: 金属有机化学
题名: HOTf-Catalyzed Rearrangement of Methylenecyclopropane Aryl and Alkyl Alcohols
其他题名: 三氟甲磺酸催化的亚甲基环丙烷芳基醇和烷基醇的重排反应
作者: Tang XY(唐翔鹰) ; Shi M(施敏)
通讯作者: 施敏
刊名: Eur. J. Org. Chem.
发表日期: 2010
期: 21, 页:4106-4110
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: An efficient method to synthesize multisubstituted naphthalene and cyclobutanol derivatives through ring opening/ring enlargement of readily available methylenecyclopropane diaryl alcohols or dialkyl- and monoalkyl- as well as monoaryl alcohols in moderate to good yields has been described in this paper. The formation of naphthalene derivatives is a sequential reaction involving a cation-induced ring opening of cyclopropane, a Friedel Crafts alkylation reaction, followed by aromatization. On the other hand, the production of cyclobutanol derivatives is a cation-induced ring-enlargement process. The scope and limitations have also been presented.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000280729500015
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/10356
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Tang XY,Shi M. HOTf-Catalyzed Rearrangement of Methylenecyclopropane Aryl and Alkyl Alcohols[J]. Eur. J. Org. Chem.,2010(21):4106-4110.
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