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学科主题: 金属有机化学
题名: Reactions of vinylidenecyclopropanes with xanthydrol and xanthene
其他题名: 亚乙烯基环丙烷和xanthydrol以及xanthene的加成反应
作者: Yuan W(袁渭) ; Shi M(施敏)
通讯作者: 施敏
刊名: Tetrahedron
发表日期: 2010
卷: 66, 期:35, 页:7104-7111
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: Vinylidenecyclopropanes undergo ring-opening reactions with xanthydrol in the presence of BF3 center dot OEt2 or with xanthene in the presence of DDQ at 0 degrees C in 1,2-dichloroethane to give the corresponding conjugate triene derivatives in moderate to good yields. Plausible reaction mechanisms have been discussed on the basis of previous literature and the control experiments. The further transformation of these trienes has been disclosed in DCE in the presence of BF3 center dot OEt2 along with a plausible reaction mechanism. (C) 2010 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000281298900006
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/10352
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Yuan W,Shi M. Reactions of vinylidenecyclopropanes with xanthydrol and xanthene[J]. Tetrahedron,2010,66(35):7104-7111.
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