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学科主题: 金属有机化学
题名: Asymmetric catalytic aza-Morita-Baylis-Hillman reaction using chiral bifunctional phosphine amides as catalysts
其他题名: 双官能团手性酰胺-膦催化的磺酰亚胺和活化烯的不对称aza-Morita–Baylis–Hillman反应
作者: Qi MJ(齐明娟) ; Teng Ai ; Shi M(施敏) ; Li GG(李桂根)
通讯作者: 施敏
刊名: Tetrahedron
发表日期: 2008
卷: 64, 期:7, 页:1181-1186
收录类别: SCI
部门归属: 上海有机所; 美国Textech大学
英文摘要: The asymmetric catalytic aza-Morita-Baylis-Hillman reaction of N-sulfonated imines with alpha,beta-unsaturated ketones has been successfully conducted by using chiral bifunctional phosphine amides as catalysts. A series of new chiral bifunctional phosphine amides were designed, synthesized, and systematically studied for this asymmetric reaction. The corresponding aza-MBH adducts were obtained in good yields (75-99%) and up to very good enantiomeric excesses (51-95% ee) under mild conditions. (c) 2007 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000253280200002
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/10332
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Qi MJ,Teng Ai,Shi M,et al. Asymmetric catalytic aza-Morita-Baylis-Hillman reaction using chiral bifunctional phosphine amides as catalysts[J]. Tetrahedron,2008,64(7):1181-1186.
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