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学科主题: 金属有机化学
题名: Reactions of Monoaryl-Substituted Methylenecyclobutanes and Methylenecyclopropanes with 1-Hydroxybenzotriazole (HOBt), 1-Hydroxy-7-azabenzotriazole (HOAt), and 1-Hydroxysuccinimide (HOSu)
其他题名: 单芳基取代的亚甲基环丙烷和HOBt,HOAt,以及HOSu的开环及加成反应
作者: Jiang M(蒋敏) ; Shi M(施敏)
刊名: J. Org. Chem.
发表日期: 2009
卷: 74, 期:6, 页:2516-2520
收录类别: SCI
部门归属: 上海有机所
英文摘要: Monoaryl-substituted methylenecyclobutanes (MCBs) and methylenecyclopropanes (MCPs) react with 1-hydroxybenzotriazole (HOBt), 1-hydroxy-7-azabenzotriazole (HOAt), and 1-hydroxysuccinimide (HOSu) smoothly to produce the corresponding cyclobutylmethanone and cyclopropylmethanone derivatives 2, 4, and 5 via a cascade epoxidation and nucleophilic addition process or the corresponding epoxides 6 in moderate to good yields under mild conditions. A plausible mechanism has been proposed on the basis of the control experiments and the isolation of the reaction intermediates.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000264111400034
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/10306
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Jiang M,Shi M. Reactions of Monoaryl-Substituted Methylenecyclobutanes and Methylenecyclopropanes with 1-Hydroxybenzotriazole (HOBt), 1-Hydroxy-7-azabenzotriazole (HOAt), and 1-Hydroxysuccinimide (HOSu)[J]. J. Org. Chem.,2009,74(6):2516-2520.
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